The Fraction of Black Body Photons in (k,dk)
Assume that a unit volume cavity contains ntotal blackbody photons in thermal equilibrium with the cavity walls. ntotal is constant. Let a vector k be associated with each photon. The direction of k is the same as the photon’s direction of propagation, and its magnitude equals 2p/l = 2pe/hc where e is the photon’s energy. Each vector k has a unique direction.
Define g(k)dk to be the fraction of the photons with |k| in (k,dk). Then ntotalg(k)dk is the number of photons with |k| in (k,dk). And of course
As previously derived, the mean photon energy is <e> = 2.7kT. Thus <k> = 2p(2.7)kT/hc, and
In postulating a form for g(k)dk we expect no photon’s energy to be either zero or infinite. And (see Eq. 1), g(k)dk must integrate to unity.
Integrals of the form have the potential of satisfying both of these requirements, as well as Eq. 2, provided n>0. Thus we postulate that
where the constants a, n and b are to be determined. In this photons case we shall use a method first worked out by Maxwell, and used on this site to derive the Maxwell-Boltzmann law for the distribution of molecular speeds in a gas.
Let the fraction of k’s with x-components in (kx,dkx) be f(kx)dkx, and similarly for (ky,dky) and (kz,dkz). Then the fraction with components in (kx,dkx) and (ky,dky) and (kz,dkz) is f(kx)f(ky)f(kz)dkxdkydkz. And the number of k’s with components in this range is Nf(kx)f(ky)f(kz)dkxdkydkz.
In k-space each k can be represented as a point (i.e., as the tip of a "displacement" vector from the origin). Since dkxdkydkz is a volume element in this space, the density of the displacement vector tips at point (kx,ky,kz) is Nf(kx)f(ky)f (kz). This density can depend only on |k|, the distance from the origin.
The number of k tips in the spherical shell of volume 4pk2dk is Ng(k)dk, and the density in this shell is Ng(k)dk/(4pk2dk). Thus
In particular, for kx=k and ky=kz=0,
where the constant C=4pf2(0).
Now Eq. 6 can be satisfied for all k only if g(k) contains a k2 term. Thus the correct choice for n in Eq. 3 is n=2, and we postulate that
From Eq. 7,
we find that
From Eq. 2 we have
we find that
Substituting in Eq. 10:
As found previously, the average value of k is
Fig. 1 plots g(k) vs. k over the range 1E-7<k<5E6 and at a temperature of 1500 Kelvin.
g(k) vs. k
Not surprisingly, the curve in Fig. 1 resembles that for the Maxwell-Boltzmann distribution. A rather interesting feature is its resemblance also to the Planck spectral distribution law for black body radiation energy density. The curves are admittedly not the same. Still, there is food for thought.k is of course proportional to e, the photon’s energy (k = 2pe/hc), and Planck exhibits the same sort of cut-off in energy (or number of photons present at temperature T) as the curve approaches the shorter wavelengths from the right.